Excess Volume for Acetylene Tetrachloride with Pyridine, Methoxybenzene, 2-Butanone and 1,4-Dioxane at 298.15K
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Excess Volume for Acetylene Tetrachloride with Pyridine, Methoxybenzene, 2-Butanone and 1,4-Dioxane at 298.15K
1Atri D. Tripathi*, 2NiKhil Rajput, 3Prakhar Kumar Dev and 4Arshan Ahmad
Original Article
Bulletin of Pure and Applied Sciences.
Chemistry , Vol.42 C, No.1
January-June 2023: P.22-26
DOI: 10.48165/bpas.2023.42C.1.4
Description
Description
Excess Volume for Acetylene Tetrachloride with Pyridine, Methoxybenzene, 2-Butanone and 1,4-Dioxane at 298.15K
1Atri D. Tripathi*, 2NiKhil Rajput, 3Prakhar Kumar Dev and 4Arshan Ahmad
Author Affiliations
1-4Dept. of Chemistry, Faculty of Engineering, Teerthanker Mahaveer University, Moradabad, Uttar Pradesh 244001, India.
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*Corresponding Author
Atri D. Tripathi, Dept. of Chemistry, Faculty of Engineering, Teerthanker Mahaveer University, Moradabad, Uttar Pradesh 244001, India.
E-mail: atri34tmu@gmail.com
Received on 29.01.2023, Revised on 27.03.2023, Approved on 17.04.2023, Accepted on 27.04.2023, Published on 20.06.2023
Abstract
ABSTRACT
A dilatometric measurement have been carried out for getting excess volumes, VE, in the liquid state for mixtures of acetylene tetrachloride (CHCl2CHCl2), with pyridine (C5H5N), methoxybenzene (C6H5O CH3), 2-butanone (CH3COC2H5) and 1,4-dioxane (1,4-C4H8O2) at 298.15K and under atmospheric pressure. The values of excess molar volume, VE, are negative in sign for all the mixtures over whole composition range. Obtained data have been fitted by Redlich-Kister type polynomial smoothing equation. The results are discussed in the light of molecular interactions occurred between components in the liquid state.
Keywords: Excess Volume, Acetylene Tetrachloride, Pyridine, Methoxybenzene
